Peanut Butter Chocolate Cake As seen on Butternut bakery Bookmark recipe Print recipe Download recipe Share Total Time 2 hours 40 minutes Prep Time 1 hour Cook Time 40 minutes Rating 5 out of 5 stars (0) Ingredients 10-12 slices Chocolate Cake2 1/4 cups (300g) all purpose flour* see notes for GF option1 cup (90g) dutch process cocoa powder1 1/2 tsp baking powder1 tsp baking soda1/2 tsp kosher salt2 cups (400g) granulated sugar1/2 cup (110g) vegetable oil3 large eggs, room temp1 tbsp vanilla extract1 cup (235ml) milk, room temp1 tsp apple cider vinegar, or white vinegar3/4 cup (180ml) hot water1 tbsp instant espresso powderPeanut Butter Buttercream1/2 cup (110g) unsalted butter, room temp1 cup (250g) creamy no-stir peanut butter2 cups (220g) powdered sugar2–3 tbsp milkChocolate Ganache2 oz dark chocolate (about 1/4 cup chocolate)1/4 cup (60ml) heavy creamPeanut butter cups (regular and mini), for decoratingFinely chopped salted roasted peanuts, for decorating Calories DessertsKid-FriendlyBakingDairyEggsDinner PartiesIntermediateSweetCreamyBirthdays ... How would you rate this recipe? 1 stars 2 stars 3 stars 4 stars 5 stars Preparation Inline ingredients (beta) Cook mode Click to complete Step 1 Preheat the oven to 350F. Spray the inside of 3 6″ cake pans with nonstick spray and line the bottoms with parchment paper. Also fit the pans with cake strips if using. Step 2 First, stir together the milk and vinegar in a measuring glass and set aside. Step 3 In a medium bowl, whisk together the flour, cocoa, baking powder, baking soda, and salt. Step 4 In a large mixing bowl, whisk together the sugar, oil, eggs, and vanilla, followed by the milk and vinegar mixture. Step 5 In another measuring glass, mix together hot water and espresso powder. Step 6 Dump the dry ingredients into the large bowl of wet ingredients and whisk together as best you can (the dry ingredients will resist at first but just keep mixing and it will slowly come together). Step 7 With some dry ingredient swirls still visible in the mix, pour in the hot coffee and continue to whisk until smooth. Step 8 Distribute the batter between the three cake pans and bake for 35-40 minutes. They’re done when a toothpick in the center comes out clean with a few moist crumbs. Step 9 Allow the cakes to cool inside their pans for about 15 minutes, then turn the cakes out onto a cooling rack to cool completely before moving on. Step 10 When the cakes are completely cooled, make the frosting. Step 11 In a large bowl using a hand or stand mixer with the paddle attachment, mix together the butter and peanut butter until smooth. Scrape down the bowl and mix again. Step 12 Mix in the powdered sugar one cup at a time. The buttercream should appear thick and slightly lumpy after the second cup. Mix in 1 tablespoon of milk at a time to smooth out the buttercream. It should be smooth and creamy but still thick and sturdy. Step 13 To turn 3 cake layers into 6, first level off the tops of each cake either by hand with a knife or use a cake leveler. Step 14 Once all the layers have an even top, go back and cut each layer in half like a hamburger bun. This can again be done by hand with a large knife or use a cake leveler. Step 15 To stack the cake, spread about 3/4 cup of frosting between each layer. This buttercream recipe makes just enough for the layers of this cake so you shouldn’t have any left at the end. Step 16 Spread the buttercream all the way out to the edge and then some. Then once all the layers are stacked, go back and smooth out the buttercream edges to that they’re flush with the cake. This will create a naked cake effect. Step 17 Transfer the cake to the refrigerator to chill while you make the ganache. Step 18 Add the chocolate to a dish and the heavy cream to a heat safe measuring glass. Microwave the cream for about 1 minute or until bubbly and steaming. Step 19 Pour the hot cream over the chocolate and let it sit for a couple minutes, then whisk to combine. Step 20 Transfer the ganache to the refrigerator to chill for about 15 minutes. Do not pour the hot ganache over the cake as it will just drip off the cake. Step 21 To test if the ganache is ready to drip, place a small spoonful of ganache off the side of the cake. If it drips down and stops halfway or before it reaches the bottom of the cake, it’s ready. Step 22 Pour the ganache around the top edge of the cake and allow it to drip off the sides. Return the cake to the refrigerator for 10 minutes to allow the ganache to thicken (this creates the perfect consistency to allow all the peanut butter cups to stick). Step 23 When the ganache still appears glossy but visibly thickened, arrange the peanut butter cups on top followed by a sprinkle of chopped nuts. All that’s left to do is slice and enjoy! Chef’s notes GLUTEN FREE – Replace this chocolate cake with my gluten free chocolate cake recipe for a gluten free version.